An examination of the 13C NMR spectrum of tribenzoylphosphine over the temperature range -75 to +70°C fails to disclose any evidence for hindered rotation about the PC bonds, contrary to a previous claim.
The barrier to carbon-phosphorus rotation in tribenzoylphosphine. An experimental reinvestigation / D. Kost, F. Cozzi, K. Mislow. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 20:22(1979), pp. 1983-1986. [10.1016/S0040-4039(01)86243-2]
The barrier to carbon-phosphorus rotation in tribenzoylphosphine. An experimental reinvestigation
F. CozziSecondo
;
1979
Abstract
An examination of the 13C NMR spectrum of tribenzoylphosphine over the temperature range -75 to +70°C fails to disclose any evidence for hindered rotation about the PC bonds, contrary to a previous claim.
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