Two new cyclopropane triterpene glycosides were isolated from the methanol extracts of leaves of Passiflora quadrangularis. On the basis of hydrolysis, spectral evidence and comparison with quadranguloside, these compounds were assigned the structures 9,19-cyclolanosta-22,25-epoxy-3β-21,22(R)-triol-3β-O-gentiobioside and 9,19-cyclolanosta-21,24-epoxy-3β-25,26-triol-3β-O-gentiobioside,respectively. Oleanolic acid-3-sophoroside was also isolated for the first time from a natural source.

Triterpene glycosides related to quadranguloside from Passiflora quadrangularis / F. Orsini, F. Pelizzoni, G. Ricca, L. Verotta. - In: PHYTOCHEMISTRY. - ISSN 0031-9422. - 26:4(1987), pp. 1101-1105. [10.1016/S0031-9422(00)82358-4]

Triterpene glycosides related to quadranguloside from Passiflora quadrangularis

F. Orsini
Primo
;
F. Pelizzoni
Secondo
;
L. Verotta
Ultimo
1987

Abstract

Two new cyclopropane triterpene glycosides were isolated from the methanol extracts of leaves of Passiflora quadrangularis. On the basis of hydrolysis, spectral evidence and comparison with quadranguloside, these compounds were assigned the structures 9,19-cyclolanosta-22,25-epoxy-3β-21,22(R)-triol-3β-O-gentiobioside and 9,19-cyclolanosta-21,24-epoxy-3β-25,26-triol-3β-O-gentiobioside,respectively. Oleanolic acid-3-sophoroside was also isolated for the first time from a natural source.
cyclopropane triterpene glycosides; oleanolic acid-3-sophoroside.; Passiflora quadrangularis; Passifloraceae; quadranguloside
Settore CHIM/06 - Chimica Organica
1987
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/181638
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