The synthetically useful chiral synthons R and S (4E)-2-methyl-4-hexen-1-ol (1a) can be prepared enantiomerically pure by an enantioselective transacetylation with vinyl acetate of racemic 1a in dichloromethane catalyzed by a lipase from Pseudomonas fluorescens (PFL).
Enzymatic synthesis of enantiomerically pure chiral synthons: Lipase-catalyzed resolution of (R / S, 4 E)-2-Methyl-4-hexen-l-ol / P. Ferraboschi, D. Brembilla, P. Grisenti, E. Santaniello. - In: SYNLETT. - ISSN 0936-5214. - :5(1991), pp. 310-312.
Enzymatic synthesis of enantiomerically pure chiral synthons: Lipase-catalyzed resolution of (R / S, 4 E)-2-Methyl-4-hexen-l-ol
P. FerraboschiPrimo
;E. SantanielloUltimo
1991
Abstract
The synthetically useful chiral synthons R and S (4E)-2-methyl-4-hexen-1-ol (1a) can be prepared enantiomerically pure by an enantioselective transacetylation with vinyl acetate of racemic 1a in dichloromethane catalyzed by a lipase from Pseudomonas fluorescens (PFL).
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