The point defect parameters, viz. formation energy and molar ratio of free Schottky defects, in the (Cs,Tl)Cl solid solution with the CsCl type structure, beta, have been computed by following the procedure already proposed for (Cs,Tl)Br (see ibid., vol.110, p.1, 1978) which implies the previous computation of the ionic migration energies and transport numbers. As for the solid solution with the NaCl type structure, alpha, which has been recognized in this system only the ionic transport numbers and the formation energy for a pair of Schottky defects have been obtained
Point defect parameters in the system CsCl-TlCl / A. Schiraldi, E. Pezzati. - In: ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE. - ISSN 0044-3336. - 113:2(1978), pp. 179-188. [10.1524/zpch.1978.113.2.179]
Point defect parameters in the system CsCl-TlCl
A. SchiraldiPrimo
;
1978
Abstract
The point defect parameters, viz. formation energy and molar ratio of free Schottky defects, in the (Cs,Tl)Cl solid solution with the CsCl type structure, beta, have been computed by following the procedure already proposed for (Cs,Tl)Br (see ibid., vol.110, p.1, 1978) which implies the previous computation of the ionic migration energies and transport numbers. As for the solid solution with the NaCl type structure, alpha, which has been recognized in this system only the ionic transport numbers and the formation energy for a pair of Schottky defects have been obtained
Pubblicazioni consigliate
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
