AgClO4 reacts with hexamethylenetetramine (hmt) in ethanol-CH2Cl2 in the ratio 1:1 to yield the two-dimensional polymer [Ag(hmt)] ClO4, consisting of hexagonal meshed layers, while a twofold excess of AgClO4 produces [Ag-3-(hmt)(2)]ClO4](3) . 2H(2)O, in which Ag-I ions intercalate between the sheets of the two-dimensional polymer, joining them as spacers to give a three-dimensional (3,4)-connected open network of uncommon topological type.
Self-assembly of a three-dimensional network from two-dimensional layers via metallic spacers: The (3,4)-connected frame of [Ag-3(hmt)(2)][ClO4](3)center dot 2H(2)O (hmt equals hexamethylenetetramine) / L. Carlucci, G. Ciani, D. vonGudenberg, D.M. Proserpio, A. Sironi. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - :6(1997), pp. 631-632.
Self-assembly of a three-dimensional network from two-dimensional layers via metallic spacers: The (3,4)-connected frame of [Ag-3(hmt)(2)][ClO4](3)center dot 2H(2)O (hmt equals hexamethylenetetramine)
L. CarlucciPrimo
;G. CianiSecondo
;D.M. ProserpioPenultimo
;A. SironiUltimo
1997
Abstract
AgClO4 reacts with hexamethylenetetramine (hmt) in ethanol-CH2Cl2 in the ratio 1:1 to yield the two-dimensional polymer [Ag(hmt)] ClO4, consisting of hexagonal meshed layers, while a twofold excess of AgClO4 produces [Ag-3-(hmt)(2)]ClO4](3) . 2H(2)O, in which Ag-I ions intercalate between the sheets of the two-dimensional polymer, joining them as spacers to give a three-dimensional (3,4)-connected open network of uncommon topological type.
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