Efficient, stereocontrolled total synthesis of the title compound is described. starting from enantiopure intermediates. A key step was the diastereoselective catalytic hydrogenation of a pentacyclic oxazepinohexahydroindolo[2,3-a]quinolizine derivative. (C) 2001 Elsevier Science Ltd. All rights reserved.
Stereocontrolled reduction of an oxazepinohexahydroindolo[2,3-a]quinolizine derivative: asymmetric total synthesis of (+)-tacamonine / B. Danieli, G. Lesma, D. Passarella, A. Sacchetti, A. Silvani. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 42:41(2001), pp. 7237-7240.
Stereocontrolled reduction of an oxazepinohexahydroindolo[2,3-a]quinolizine derivative: asymmetric total synthesis of (+)-tacamonine
B. DanieliPrimo
;G. LesmaSecondo
;D. Passarella;A. SilvaniUltimo
2001
Abstract
Efficient, stereocontrolled total synthesis of the title compound is described. starting from enantiopure intermediates. A key step was the diastereoselective catalytic hydrogenation of a pentacyclic oxazepinohexahydroindolo[2,3-a]quinolizine derivative. (C) 2001 Elsevier Science Ltd. All rights reserved.
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