The complex between TiCl4 and PPh effectively catalyses the aldol addition of silyl ketene acetals to aldehydes dramatically improving the anti-syn ratios.
IMPROVED ENANTIOSELECTIVE SYNTHESIS OF ANTI ALPHA-METHYL-BETA-HYDROXYESTERS THROUGH TICL4-PPH3 MEDIATED ALDOL CONDENSATION / C. PALAZZI, L. COLOMBO, C.M.A. GENNARI. - In: TETRAHEDRON LETTERS. - ISSN 0040-4039. - 27:15(1986), pp. 1735-1738.
IMPROVED ENANTIOSELECTIVE SYNTHESIS OF ANTI ALPHA-METHYL-BETA-HYDROXYESTERS THROUGH TICL4-PPH3 MEDIATED ALDOL CONDENSATION
C.M.A. GENNARI
1986
Abstract
The complex between TiCl4 and PPh effectively catalyses the aldol addition of silyl ketene acetals to aldehydes dramatically improving the anti-syn ratios.
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