Evidence is presented that the first step of the biosynthesis of ascochitine (1), a metabolite of Ascochyta fabae Speg., involves methylation of a hexaketide, followed by cyclization, reduction to the aldehyde, dehydration, and eventually oxidation of the methyl group at C(7) to a carboxy group.
Biosynthesis of ascochitine: Incorporation studies with advanced precursors / L. Colombo, C.M.A. Gennari, C. Scolastico, F. Aragozzini, C. Merendi. - In: JOURNAL OF THE CHEMICAL SOCIETY, CHEMICAL COMMUNICATIONS. - ISSN 0022-4936. - :11(1979), pp. 492-493. [10.1039/C39790000492]
Biosynthesis of ascochitine: Incorporation studies with advanced precursors
C.M.A. Gennari;C. Scolastico;
1979
Abstract
Evidence is presented that the first step of the biosynthesis of ascochitine (1), a metabolite of Ascochyta fabae Speg., involves methylation of a hexaketide, followed by cyclization, reduction to the aldehyde, dehydration, and eventually oxidation of the methyl group at C(7) to a carboxy group.
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