A strategy featuring a key retrosynthetic disconnection at the C2-C3 position was applied to the total synthesis of the common diterpenoid tricyclic skeleton of sarcodictyins and eleutherobin. Fully functionalized cyclization precursors were accessed via a brief and convergent route, making use of unprecedented synthetic transformations. (C) 2001 Elsevier Science Ltd. All rights reserved.
Synthetic studies on the sarcodictyins: synthesis of fully functionalized cyclization precursors / S.M. Ceccarelli, U. Piarulli, C.M.A. Gennari. - In: TETRAHEDRON. - ISSN 0040-4020. - 57:40(2001), pp. 8531-8542. [10.1016/S0040-4020(01)00739-6]
Synthetic studies on the sarcodictyins: synthesis of fully functionalized cyclization precursors
C.M.A. GennariUltimo
2001
Abstract
A strategy featuring a key retrosynthetic disconnection at the C2-C3 position was applied to the total synthesis of the common diterpenoid tricyclic skeleton of sarcodictyins and eleutherobin. Fully functionalized cyclization precursors were accessed via a brief and convergent route, making use of unprecedented synthetic transformations. (C) 2001 Elsevier Science Ltd. All rights reserved.
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