Organometallic complexes of transition-metals have recently received considerable attention as phosphorescent emitters for Organic Light Emitting Diodes (OLEDs), owing to their remarkable luminescent properties [1]. In particular, halide complexes of platinum (II) based on cyclometallated 1,3-di(2-pyridyl)benzene ligand seem very promising in this respect because they are highly emissive [2]. Besides, it is well known that the substitution of weak-field halide ligands by strong-field acetylide, R–CC–, provides an example of how an increase in the ligand field strength of the ancillary ligand can promote luminescence [3]. These observations prompted us to prepare new cyclometallated Pt(II) complexes with a substituted 1,3-di(2-pyridil)benzene ligand (see figure) to get a better understanding of the effect on the emission and quantum yields of different R substituents and various acetylide ancillary ligands. It turned out that the prepared complexes are highly luminescent and can be used for the preparation of light-emitting devices. Details on this study will be presented. R = Me, Mesityl Y = 3,5-difluorobenzene; dimethyl-phenyl-amine, pentafluorobenzene [1] Evans, R.C.; Douglas, P.; Winscom, C.J. Coord. Chem. Rev. 2006, 250, 2093. [2] Murphy, L.; Williams, J.A.G. in Topics in Organometallic Chemistry 28. Molecular Organometallic Materials for Optics, Le Bozec, H. and Guerchais V. (eds.), Springer Verlag Berlin Heidelberg 2010, pp 75-111. [3] Williams, J. A. G.; Develay, S.; Rochester, D. L.; Murphy, L. Coord. Chem. Rev., 2008, 252, 2596; Lu,W.; Mi, B.-X.; Chan, M. C. W.; Hui, Z.; Che, C.-M.; Zhu, N.; Lee, S.-T. J. Am. Chem. Soc., 2004, 126, 4958.

Novel cyclometallated pincer of pt(ii) alkyne complexes with interesting luminescent properties / E. Rossi, A. Colombo, S. Ordanini, C. Dragonetti, D.M. Roberto, J.A.G. Williams. ((Intervento presentato al 19. convegno International Symposium on the Photophysics and photochemistry of coordination compounds tenutosi a Strasburgo nel 2011.

Novel cyclometallated pincer of pt(ii) alkyne complexes with interesting luminescent properties

E. Rossi
Primo
;
A. Colombo
Secondo
;
S. Ordanini;C. Dragonetti;D.M. Roberto
Penultimo
;
2011

Abstract

Organometallic complexes of transition-metals have recently received considerable attention as phosphorescent emitters for Organic Light Emitting Diodes (OLEDs), owing to their remarkable luminescent properties [1]. In particular, halide complexes of platinum (II) based on cyclometallated 1,3-di(2-pyridyl)benzene ligand seem very promising in this respect because they are highly emissive [2]. Besides, it is well known that the substitution of weak-field halide ligands by strong-field acetylide, R–CC–, provides an example of how an increase in the ligand field strength of the ancillary ligand can promote luminescence [3]. These observations prompted us to prepare new cyclometallated Pt(II) complexes with a substituted 1,3-di(2-pyridil)benzene ligand (see figure) to get a better understanding of the effect on the emission and quantum yields of different R substituents and various acetylide ancillary ligands. It turned out that the prepared complexes are highly luminescent and can be used for the preparation of light-emitting devices. Details on this study will be presented. R = Me, Mesityl Y = 3,5-difluorobenzene; dimethyl-phenyl-amine, pentafluorobenzene [1] Evans, R.C.; Douglas, P.; Winscom, C.J. Coord. Chem. Rev. 2006, 250, 2093. [2] Murphy, L.; Williams, J.A.G. in Topics in Organometallic Chemistry 28. Molecular Organometallic Materials for Optics, Le Bozec, H. and Guerchais V. (eds.), Springer Verlag Berlin Heidelberg 2010, pp 75-111. [3] Williams, J. A. G.; Develay, S.; Rochester, D. L.; Murphy, L. Coord. Chem. Rev., 2008, 252, 2596; Lu,W.; Mi, B.-X.; Chan, M. C. W.; Hui, Z.; Che, C.-M.; Zhu, N.; Lee, S.-T. J. Am. Chem. Soc., 2004, 126, 4958.
2011
Settore CHIM/03 - Chimica Generale e Inorganica
Novel cyclometallated pincer of pt(ii) alkyne complexes with interesting luminescent properties / E. Rossi, A. Colombo, S. Ordanini, C. Dragonetti, D.M. Roberto, J.A.G. Williams. ((Intervento presentato al 19. convegno International Symposium on the Photophysics and photochemistry of coordination compounds tenutosi a Strasburgo nel 2011.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/165996
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