We report here on three new 1-D polymeric species, obtained by self-assembly of Rh(I) and Ir(I) complexes of general formula [M(CO)2Cl2]2 (M= Rh, Ir) with bidentate phosphine ligands as 1,2-bis(diphenylphosphino)acetylene (dppa) and trans-1,2-bis(diphenylphosphino)ethene (dppethe).
Carbonyl complexes of Rh(I) and Ir(I) and P-donor ligands as useful ‘‘building blocks’’ for the self-assembly of new organometallic polymers / G. Peli, S. Rizzato, S. Cassese, L. Garlaschelli, M. Manassero. - In: CRYSTENGCOMM. - ISSN 1466-8033. - 2005:7(2005), pp. 575-577.
Carbonyl complexes of Rh(I) and Ir(I) and P-donor ligands as useful ‘‘building blocks’’ for the self-assembly of new organometallic polymers
G. PeliPrimo
;S. RizzatoSecondo
;S. Cassese;L. GarlaschelliPenultimo
;M. ManasseroUltimo
2005
Abstract
We report here on three new 1-D polymeric species, obtained by self-assembly of Rh(I) and Ir(I) complexes of general formula [M(CO)2Cl2]2 (M= Rh, Ir) with bidentate phosphine ligands as 1,2-bis(diphenylphosphino)acetylene (dppa) and trans-1,2-bis(diphenylphosphino)ethene (dppethe).
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