The formation of two organic interpenetrated networks on halogen bonding driven self-assembly of diiodoperfluorarenes with tetrapyridyl tectons is described. Both architectures exhibit two-dimensional square 4^4 networks; with either a 2-fold interpenetration of class IIa or a 3-fold interpenetration of class Ia. Diiodoperfluoroarenes are proven robust tectons in the design of interpenetrated networks based on the expansion strategy.
Halogen-bonded and interpenetrated networks through the self-assembly of diiodoperfluoroarene and tetrapyridyl tectons / M. Baldrighi, P. Metrangolo, F. Meyer, T. Pilati, D. M. Proserpio, G. Resnati, G. Terraneo. - In: JOURNAL OF FLUORINE CHEMISTRY. - ISSN 0022-1139. - 131:11(2010), pp. 1218-1224. [10.1016/j.jfluchem.2010.06.001]
Halogen-bonded and interpenetrated networks through the self-assembly of diiodoperfluoroarene and tetrapyridyl tectons
D.M. Proserpio;
2010
Abstract
The formation of two organic interpenetrated networks on halogen bonding driven self-assembly of diiodoperfluorarenes with tetrapyridyl tectons is described. Both architectures exhibit two-dimensional square 4^4 networks; with either a 2-fold interpenetration of class IIa or a 3-fold interpenetration of class Ia. Diiodoperfluoroarenes are proven robust tectons in the design of interpenetrated networks based on the expansion strategy.
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