CoII sulfate reacts with the flexible ligand 1,4-bis(imidazol-1-ylmethyl)benzene (bix) to yield the coordination network [Co(bix)2(H2O)2](SO4)·7H2O, containing polymeric ribbons of rings which penetrate and catenate a 3D single frame of the CdSO4 topology, to produce an open-channel entangled architecture with nanoporous behaviour.

A new type of entanglement involving one-dimensional ribbons of rings catenated to a three-dimensional network in the nanoporous structure of [Co(bix)2(H2O)2](SO4)·7H2O [bix = 1,4-bis(imidazol-1-ylmethyl)benzene] / L. Carlucci, G.M. Ciani, D.M. Proserpio. - In: CHEMICAL COMMUNICATIONS. - ISSN 1359-7345. - 10:4(2004), pp. 380-381.

A new type of entanglement involving one-dimensional ribbons of rings catenated to a three-dimensional network in the nanoporous structure of [Co(bix)2(H2O)2](SO4)·7H2O [bix = 1,4-bis(imidazol-1-ylmethyl)benzene]

L. Carlucci
Primo
;
G.M. Ciani
Secondo
;
D.M. Proserpio
Ultimo
2004

Abstract

CoII sulfate reacts with the flexible ligand 1,4-bis(imidazol-1-ylmethyl)benzene (bix) to yield the coordination network [Co(bix)2(H2O)2](SO4)·7H2O, containing polymeric ribbons of rings which penetrate and catenate a 3D single frame of the CdSO4 topology, to produce an open-channel entangled architecture with nanoporous behaviour.
Settore CHIM/03 - Chimica Generale e Inorganica
2004
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2434/144628
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