An interesting coordination complex based on a designed X ligand has been prepared. It displays a novel 4-connected uninodal net with point symbol (4^2.6^3.8) and vertex symbol [4.6.4.6.6.10(12)] which has never been observed in metal-organic frameworks/coordination polymers. Meanwhile, the compound displays intriguing structural features of interpenetration and selfcatenation, as well as nonlinear optical properties.
New Metal-Organic Framework with Uninodal 4-Connected Topology Displaying Interpenetration, Self-Catenation, and Second-Order Nonlinear Optical Response / T.-F. Liu, J. Lü, Z. Guo, D. M. Proserpio, R. Cao. - In: CRYSTAL GROWTH & DESIGN. - ISSN 1528-7483. - 10:4(2010), pp. 1489-1491. [10.1021/cg100174h]
New Metal-Organic Framework with Uninodal 4-Connected Topology Displaying Interpenetration, Self-Catenation, and Second-Order Nonlinear Optical Response
D.M. ProserpioPenultimo
;
2010
Abstract
An interesting coordination complex based on a designed X ligand has been prepared. It displays a novel 4-connected uninodal net with point symbol (4^2.6^3.8) and vertex symbol [4.6.4.6.6.10(12)] which has never been observed in metal-organic frameworks/coordination polymers. Meanwhile, the compound displays intriguing structural features of interpenetration and selfcatenation, as well as nonlinear optical properties.
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